Access Type
Open Access Dissertation
Date of Award
January 2011
Degree Type
Dissertation
Degree Name
Ph.D.
Department
Chemistry
First Advisor
Arthur G. Suits
Abstract
This work presents results of primary fundamental photodissociation and state-specific ion-molecule dynamical studies that are relevant to understanding the formation and growth mechanisms of unsaturated hydrocarbon molecules, haze layers and aerosols in Titan's upper atmosphere. In the diacetylene dimer, it is shown, via laboratory studies combined with electronic structure calculations that the photodissociation of the dimer readily initiates atomic hydrogen (H) loss and atomic H transfer reactions forming two prototypes of resonantly stabilized free radicals, C8H3 and C4H3, respectively. In ethylamine cation, high-level ab initio calculations identify the complex dissociation pathways for the ground state CH3CH2NH2+ radical cation at 233.3 nm using Direct current (DC) slice imaging technique, revealing important features of the potential surface that are important in Titan's ion-molecule reactions. Finally, a new technique is implemented to measure the branching ratios for the reactions of state-prepared N2+ ions with methane (CH4), acetylene (C2H2) ethylene (C2H4), Hydrogen (H2) and acetonitrile (CH3CN) under a rotational temperature ~40 ± 5K.
Recommended Citation
Gichuhi, Wilson Kamundia, "Astrochemical dynamics: Fundamental studies relevant to titan's atmosphere" (2011). Wayne State University Dissertations. 274.
https://digitalcommons.wayne.edu/oa_dissertations/274